Q1.Prove that PV^Y=C for reversible adiabatic process. Solution: δQ = dU + PdV Reversible Adiabatic: δQ=0 (:: There is no heat interaction between system and surroundings = adiabatic dU + dV = 0 dU = -PdV m(Cv)dT = -PdV ----------------------------------------------(1) Now we want 'Y' , so, We know H = U + PV dH = dU + PdV + VdP dH = δQ + VdP (:: There is no heat interaction δQ =0) dH = VdP m(Cp)dT = VdP ------------------------------------------(2) Dividing (2) by (1) Y = -V/P(dP/dV) (:: Y= Gama=Cp/Cv) Y = -V/dV(dP/P) Integral both side ∫YdV/V + ∫dP/P = ∫0 Y(lnV) + lnP = lnC ln PV^Y = lnC PV^Y = C ------------Since, this has been found for δQ =0 so, only apply it for reversible adiabatic