Q1.Prove that PV^Y=C for reversible adiabatic process. Solution: δQ = dU + PdV Reversible Adiabatic: δQ=0 (:: There is no heat interaction between system and surroundings = adiabatic dU + dV = 0 dU = -PdV m(Cv)dT = -PdV ----------------------------------------------(1) Now we want 'Y' , so, We know H = U + PV dH = dU + PdV + VdP dH = δQ + VdP (:: There is no heat interaction δQ =0) dH = VdP m(Cp)dT = VdP ------------------------------------------(2) Dividing (2) by (1) Y = -V/P(dP/dV) (:: Y= Gama=Cp/Cv) Y = -V/dV(dP/P) Integral both side ∫YdV/V + ∫dP/P = ∫0 Y(lnV) + lnP = lnC ln PV^Y = lnC PV^Y = C ------------Since, this has been found for δQ =0 so, only apply it for reversible adiabatic
Q. A 1 gm nitrogen undergoes a following sequence of process in a piston cylinder arrangement.(1) An adiabatic expansion in which volume double. (2) A constant pressure process in which volume is reduced to its initial state. Represent the cycle on p -v diagram, calculate net work done by the gas.
Q. A 1 gm nitrogen undergoes a following sequence of process in a piston cylinder arrangement.(1) An adiabatic expansion in which volume double. (2) A constant pressure process in which volume is reduced to its initial state. Represent the cycle on p -v diagram, calculate net work done by the gas. Assuming t1 = 150°C , P1 = 5 atm, Y = 1.4, R = 297 J/kg K. Solution: t1 = 150°C T1 = 150 + 273 = 423 K P1 = 5 × 1.01325 = 5.06625 bar Process (1-2): T2/T1 = (V1/V2)^Y-1 T2/423 = (V1/2V1)^1.4-1 T2 = 320.5K Process(2-3): T3/T2 = V1/V2 T3/T2 = V1/2V1 T3 = T2/2 T3=320.5/2=160.25K Now : W(net) = W(1-2) + W(2-3) + W(3-1) W(net) = P1V1 -P2V2/Y-1 + P3V3 -P2V2 + 0 W(net) = mR(T1-T2)/Y-1 + mR(T3-T2) W(net) = 10^-3 × 297(423 - T2)/1.4 -1 + 10^-3×297(T3 - T2) W(net) = 10^-3 × 297(423 - 320.5)/0.4 + 10^-3×297(160.25 - 320.5) W(net) = 28.86 J